Badanie procesu starzenia asfaltu modyfikowanego polimerami przy zastosowaniu  zmodyfikowanej metody cienkiej warstwy w aspekcie recyklingu

Miftah Farid; Jan Król

doi:10.7409/rabdim.023.020

Published: 2023-12-30

Vol. 22 No. 4 (2023)

Investigating the ageing process of polymer modified bitumen using a modified Thin-Film Oven Test in the aspect of recycling purpose

Miftah Farid

, Jan Król

Section: Articles

https://doi.org/10.7409/rabdim.023.020

Abstract

Polymer Modified Bitumen (PMB) is a widely used material for road construction. Commonly, PMBs are produced by mixing bitumen with various types of Styrene- Butadiene–Styrene (SBS) copolymers and, if necessary, with another additive such as a cross-linking agent to improve the material’s performance. The ageing process of PMBs is more complex than unmodified bitumen due to molecular interactions between the bitumen and the polymer. Previous studies suggest that the polymer modifier dominates the chemical degradation of PMBs during short-term ageing, while long-term ageing is dominated by bitumen oxidation. As a result, RAP containing PMB as its binder still contains polymer in its chemical composition, emphasizing the need for a comprehensive understanding of the ageing process of PMBs. In current practice, RAP is heated before being mixed with virgin materials to allow reactivation of its aged binder. This study proposes a modified Thin-Film Oven Test (TFOT) as an ageing simulation method, with variations in time and temperature to simulate ageing during the RAP mixing process. The bitumen oxidation phenomenon mostly dominates the ageing process. From quantitative indices analysis, under short duration and lower temperature conditions, the polymer degradation helps to resist ageing shortly. Moreover, the DSR test shows that ageing caused the PMB to increase in complex modulus while decreasing in phase angle, indicating hardening and shifting toward more elastic behaviour. The most prominent effect of ageing can be observed at lower test temperature for phase angle and higher test temperature for complex modulus. Generally, the ageing conditions’ temperature has a more significant role in dictating the ageing effect on PMB than the duration.

Keywords:

polymer modified bitumen, recycling, RAP, ageing, FTIR.

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Farid, M., & Król, J. (2023). Investigating the ageing process of polymer modified bitumen using a modified Thin-Film Oven Test in the aspect of recycling purpose. Roads and Bridges - Drogi I Mosty, 22(4), 379–386. https://doi.org/10.7409/rabdim.023.020

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References

Sabadra V.: Use of polymer modified bitumen in road construction. International Research Journal of Engineering and Technology, 4, 12, 2017, 799–801
Google Scholar

Zhang J., Huang W., Zhang Y., Yan C., Lv Q., Guan W.: Evaluation of the terminal blend crumb rubber/SBS composite modified asphalt. Construction and Building Materials, 278, 2021, 122377, DOI: 10.1016/j.conbuildmat.2021.122377 DOI: https://doi.org/10.1016/j.conbuildmat.2021.122377
Google Scholar

McNally T.: Introduction to polymer modified bitumen (PmB). In: McNally T. (ed.): Polymer Modified Bitumen, Woodhead Publishing, 2011, 1–21, DOI: 10.1533/9780857093721.1 DOI: https://doi.org/10.1533/9780857093721.1
Google Scholar

Bíró S., Fazekas B.: Asphalt rubber versus other modified bitumens, 2012, api.semanticscholar.org/CorpusID:201858741
Google Scholar

Ge D., Yan K., You L., Wang Z.: Modification mechanism of asphalt modified with Sasobit and Polyphosphoric acid (PPA). Construction and Building Materials, 143, 2017, 419–428, DOI: 10.1016/j.conbuildmat.2017.03.043 DOI: https://doi.org/10.1016/j.conbuildmat.2017.03.043
Google Scholar

Honarmand M., Tanzadeh J., Beiranvand M.: Bitumen and Its Modifier for Use in Pavement Engineering. In: Hemeda S. (ed.): Sustainable Construction and Building Materials, IntechOpen, London, 2019, DOI: 10.5772/intechopen.82489 DOI: https://doi.org/10.5772/intechopen.82489
Google Scholar

Wang S., Huang W.: Investigation of ageing behavior of terminal blend rubberized asphalt with SBS polymer. Construction and Building Materials, 267, 2021, 120870, DOI: 10.1016/j.conbuildmat.2020.120870 DOI: https://doi.org/10.1016/j.conbuildmat.2020.120870
Google Scholar

Jew P., Shimizu J.A., Svazic M., Woodhams R.T.: Polyethlene-modified bitumen for paving applications. Journal of Applied Polymer Science, 31, 8, 1986, 2685–2704, DOI: 10.1002/app.1986.070310824 DOI: https://doi.org/10.1002/app.1986.070310824
Google Scholar

Liang Z.-Z., Woodhams R., Wang Z., Harbinson B.: Utilization of Recycled Polyethylene in the Preparation of Stabilized, High Performance Modified Asphalt Binders. In: Waller H. (ed.): Use of Waste Materials in Hot-Mix Asphalt, ASTM International, 1993, DOI: 10.1520/STP19851S DOI: https://doi.org/10.1520/STP19851S
Google Scholar

Yu J.-Y., Feng Z.-G., Zhang H.-L.: Ageing of polymer modified bitumen (PMB). In: McNally T. (ed.): Polymer Modified Bitumen, Woodhead Publishing, 2011, DOI: 10.1533/9780857093721.2.264 DOI: https://doi.org/10.1533/9780857093721.2.264
Google Scholar

Xing C., Liu L., Sheng J.: A new progressed mastic ageing method and effect of fillers on SBS modified bitumen ageing. Construction and Building Materials, 238, 2020, 117732, DOI: 10.1016/j.conbuildmat.2019.117732 DOI: https://doi.org/10.1016/j.conbuildmat.2019.117732
Google Scholar

Yan C., Huang W., Tang N.: Evaluation of the temperature effect on Rolling Thin Film Oven ageing for polymer modified asphalt. Construction and Building Materials, 137, 2017, 485–493, DOI: 10.1016/j.conbuildmat.2017.01.135 DOI: https://doi.org/10.1016/j.conbuildmat.2017.01.135
Google Scholar

Tian Y., Li H., Zhang H., Yang B., Zuo X., Wang H.: Comparative investigation on three laboratory testing methods for short-term ageing of asphalt binder. Construction and Building Materials, 266, 2021, 121204, DOI: 10.1016/j.conbuildmat.2020.121204 DOI: https://doi.org/10.1016/j.conbuildmat.2020.121204
Google Scholar

Mallick R.B., Brown E.R.: An evaluation of superpave binder ageing methods. International Journal of Pavement Engineering, 5, 1, 2004, 9–18, DOI: 10.1080/10298430410001720774 DOI: https://doi.org/10.1080/10298430410001720774
Google Scholar

Airey G.D.: Factors affecting the rheology of polymer modified bitumen (PMB). In: McNally T. (ed.): Polymer Modified Bitumen, Woodhead Publishing, 2011, DOI: 10.1533/9780857093721.2.238 DOI: https://doi.org/10.1533/9780857093721.2.238
Google Scholar

Xu S., Yu J., Zhang C., Sun Y.: Effect of ultraviolet ageing on rheological properties of organic intercalated layered double hydroxides modified asphalt. Construction and Building Materials, 75, 2015, 421–428, DOI: 10.1016/j.conbuildmat.2014.11.046 DOI: https://doi.org/10.1016/j.conbuildmat.2014.11.046
Google Scholar

Subhy A., Pires G.M., Lo Presti D., Airey G.: The effects of laboratory ageing on rheological and fracture characteristics of different rubberized bitumens. Construction and Building Materials, 180, 2018, 188–198, DOI: 10.1016/j.conbuildmat.2018.05.273 DOI: https://doi.org/10.1016/j.conbuildmat.2018.05.273
Google Scholar

Tarsi G., Varveri A., Lantieri C., Scarpas A., Sangiorgi C.: Effects of different ageing methods on chemical and rheological properties of bitumen. Journal of Materials in Civil Engineering, 30, 3, 2018, 04018009, DOI: 10.1061/(ASCE)MT.1943-5533.0002206 DOI: https://doi.org/10.1061/(ASCE)MT.1943-5533.0002206
Google Scholar

Petersen J.C.: Transportation Research Circular E-C140. A review of the fundamentals of asphalt oxidation: chemical, physicochemical, physical property, and durability relationships. Transportation Research Board, Washington, 2009, https://www.trb.org/Publications/Blurbs/162366.aspx
Google Scholar

Singh B., Saboo N., Kumar P.: Use of Fourier transform infrared spectroscopy to study ageing characteristics of asphalt binders. Petroleum Science and Technology, 35, 16, 2017, 1648–1654, DOI: 10.1080/10916466.2017.1350710 DOI: https://doi.org/10.1080/10916466.2017.1350710
Google Scholar

Yan C., Huang W., Ma J., Xu J., Lv Q., Lin P.: Characterizing the SBS polymer degradation within high content polymer modified asphalt using ATR-FTIR. Construction and Building Materials, 233, 2020, 117708, DOI: 10.1016/j.conbuildmat.2019.117708 DOI: https://doi.org/10.1016/j.conbuildmat.2019.117708
Google Scholar

Nivitha M.R., Prasad E., Krishnan J.M.: Ageing in modified bitumen using FTIR spectroscopy. International Journal of Pavement Engineering, 17, 7, 2016, 565–577, DOI: 10.1080/10298436.2015.1007230 DOI: https://doi.org/10.1080/10298436.2015.1007230
Google Scholar

Branthaver J.F., Petersen J.C., Robertson R.E., Duvall J.J., Kim S.S., Harnsberger P.M., Mill T., Ensley E.K., Barbour F.A., Schabron J.F.: Binder Characterization and Evaluation Vol. 2: Chemistry. Strategic Highway Research Program, National Academy of Sciences, Washington 1993
Google Scholar

Polacco G., Berlincioni S., Biondi D., Stastna J., Zanzotto L.: Asphalt modification with different polyethylene-based polymers. European Polymer Journal, 41, 12, 2005, 2831–2844, DOI: 10.1016/j.eurpolymj.2005.05.034 DOI: https://doi.org/10.1016/j.eurpolymj.2005.05.034
Google Scholar

Wilson A., Fuchs G., Scramoncin C., Martin D., Planche J.P.: Localization of the polymer phase in bitumen/polymer blends by field emission cryo-scanning electron microscopy. Energy & Fuels, 14, 3, 2000, 575–584, DOI: 10.1021/ef9902303 DOI: https://doi.org/10.1021/ef9902303
Google Scholar

Yousefi A.A.: Polyethylene dispersions in bitumen: The effects of the polymer structural parameters. Journal of Applied Polymer Science, 90, 12, 2003, 3183–3190, DOI: 10.1002/app.12942 DOI: https://doi.org/10.1002/app.12942
Google Scholar

Xiaohu L., Yohann T., Redelius P.: Ageing of bituminous binders – laboratory tests and field data. E&E Congress, Copenhagen, 2008, DOI: 10.13140/2.1.4101.2487
Google Scholar

Liu M., Ferry M.A., Davison R.R., Glover C.J., Bullin J.A.: Oxygen uptake as correlated to carbonyl growth in aged asphalts and asphalt corbett fractions. Industrial & Engineering Chemistry Research, 37, 12, 1998, 4669–4674, DOI: 10.1021/ie980450o DOI: https://doi.org/10.1021/ie980450o
Google Scholar

Lu X., Isacsson U.: Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens. Fuel, 77, 9–10, 1998 961–972, DOI: 10.1016/S0016-2361(97)00283-4 DOI: https://doi.org/10.1016/S0016-2361(97)00283-4
Google Scholar

Yan C., Huang W., Lin P., Zhang Y., Lv Q.: Chemical and rheological evaluation of ageing properties of high content SBS polymer modified asphalt. Fuel, 252, 2019, 417–426, DOI: 10.1016/j.fuel.2019.04.022 DOI: https://doi.org/10.1016/j.fuel.2019.04.022
Google Scholar

Investigating the ageing process of polymer modified bitumen using a modified Thin-Film Oven Test in the aspect of recycling purpose

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Miftah Farid

Jan Król