Effect of various de-icers containing chloride ions on scaling resistance and chloride penetration depth of highway concrete

Pavel Reiterman; Martin Keppert

doi:10.7409/rabdim.020.003

Published: 2020-03-31

Vol. 19 No. 1 (2020)

Effect of various de-icers containing chloride ions on scaling resistance and chloride penetration depth of highway concrete

Pavel Reiterman , Martin Keppert

Section: Articles

https://doi.org/10.7409/rabdim.020.003

Abstract

The use of chloride-based de-icers belongs to the most common road winter maintenance measures applied to prevent dangerous driving conditions. Chloride-based de-icers are the most frequently used worldwide. The essential difficulty with de-icers is their detrimental effect on concrete, other components of the road infrastructure and on vehicles. The interaction of various individual chloride salts with concrete is described in the paper; the experimental programme was focused on evaluation of the most frequently applied chloride-based de-icers in terms of damage to the air-entrained concrete used for highway construction. Three individual salts – NaCl, CaCl₂, MgCl₂ – and one blend (NaCl + CaCl₂) were used. Their effect on concrete was investigated in terms of surface scaling during freezing-thawing cycles, residual mechanical properties and final ingress of chloride ions. Calcium chloride exhibited the most detrimental effect on the studied concrete.

Keywords:

chloride-based de-icers, chloride ingress, freezing-thawing, residual mechanical properties, wetting-drying cycles.

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Reiterman, P., & Keppert, M. (2020). Effect of various de-icers containing chloride ions on scaling resistance and chloride penetration depth of highway concrete. Roads and Bridges - Drogi I Mosty, 19(1), 51–64. https://doi.org/10.7409/rabdim.020.003

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References

Wang K., Nelsen D.E., Nixon W.A.: Damaging effects of de-icing chemicals on concrete materials. Cement and Concrete Composites, 28, 2, 2006, 173-188, DOI: 10.1016/j.cemconcomp.2005.07.006
Google Scholar

Dang Y., Xie N., Kessel A., McVey E., Pace A., Shi X.: Accelerated laboratory evaluation of surface treatments for protecting concrete bridge decks from salt scaling. Construction and Building Materials, 55, 2014, 128-135, DOI: 10.1016/j.conbuildmat.2014.01.014
Google Scholar

Lee B.D., Choi Y.S., Kim Y.G., Kim I.S., Yang E.I.: A comparison study of performance and environmental impacts of chloride-based de-icers and eco-label certified de-icers in South Korea. Cold Regions Science and Technology, 143, 2017, 43-51, DOI: 10.1016/j.coldregions.2017.08.010
Google Scholar

Shi X., Fay L., Peterson M.M., Berry M., Mooney M.: A FESEM/EDX investigation into how continuous de-icer exposure affects the chemistry of Portland cement concrete. Construction and Building Materials, 25, 2, 2011, 957-966, DOI: 10.1016/j.conbuildmat.2010.06.086
Google Scholar

Liu Z., Hansen W.: Freezing characteristics of air-entrained concrete in the presence of de-icing salt. Cement and Concrete Research, 74, 2015, 10-18, DOI: 10.1016/j.cemconres.2015.03.015
Google Scholar

Pruckner F., Gjřrv O.: Effect of CaCl2 and NaCl additions on concrete corrosivity. Cement and Concrete Research, 34, 7, 2004, 1209-1217, DOI: 10.1016/j.cemconres.2003.12.015
Google Scholar

Xu J., Jiang L., Wang W., Jiang Y.: Influence of CaCl2 and NaCl from different sources on chloride threshold value for the corrosion of steel reinforcement in concrete. Construction and Building Materials, 25, 2, 2011, 663-669, DOI: 10.1016/j.conbuildmat.2010.07.023
Google Scholar

Shi X., Fortune K., Fay L., Smithlin R., Cross D., Yang Z., Wu J.: Longevity of corrosion inhibitors and performance of anti-icing products after pavement application: A case study. Cold Regions Science and Technology, 83-84, 2012, 89-97, DOI: 10.1016/j.coldregions.2012.06.009
Google Scholar

Shi X., Fay L., Yang Z., Nguyen T.A., Liu Y.: Corrosion of De-icers to Metals in Transportation Infrastructure: Introduction and Recent Developments. Corrosion Reviews, 27, 1-2, 2009, 23-52, DOI: 10.1515/CORRREV.2009.27.1-2.23
Google Scholar

Spragg R.P., Castro J., Li W., Pour-Ghaz M., Huang P.T., Weiss J.: Wetting and drying of concrete using aqueous solutions containing de-icing salts. Cement and Concrete Composites, 33, 5, 2011, 535-542, DOI: 10.1016/j.cemconcomp.2011.02.009
Google Scholar

Egüez Álava H., De Belie N., De Schutter G.: Proposed mechanism for the formation of oxychloride crystals during sodium chloride application as a de-icer salt in carbonated concrete. Construction and Building Materials, 109, 2016, 188-197, DOI: 10.1016/j.conbuildmat.2016.01.047
Google Scholar

Tian W., Han N.: Pore characteristics (>0.1 mm) of non-air entrained concrete destroyed by freeze-thaw cycles based on CT scanning and 3D printing. Cold Regions Science and Technology, 151, 2018, 314-322, DOI: 10.1016/j.coldregions.2018.03.027
Google Scholar

Suprenant B.A.: Freezing concrete as a construction practice. Cold Regions Science and Technology, 11, 2, 1985, 195-197, DOI: 10.1016/0165-232X(85)90018-7
Google Scholar

Bager D.H., Sellevold E.J.: Ice formation in hardened cement paste, Part II - drying and resaturation on room temperature cured pastes. Cement and Concrete Research, 16, 6, 1986, 835-844, DOI: 10.1016/0008-8846(86)90006-2
Google Scholar

Shang H., Song Y., Ou J.: Behaviour of air-entrained concrete after freeze-thaw cycles. Acta Mechanica Solida Sinica. 22, 3, 2009, 261-266, DOI: 10.1016/S0894-9166(09)60273-1
Google Scholar

Farnam Y., Wiese A., Bentz D., Davis J., Weiss J.: Damage development in cementitious materials exposed to magnesium chloride de-icing salt. Construction and Building Materials, 93, 2015, 384-392, DOI: 10.1016/j.conbuildmat.2015.06.004
Google Scholar

Qiao C., Suraneni P., Weiss J.: Damage in cement pastes exposed to NaCl solutions. Construction and Building Materials, 171, 2018, 120-127, DOI: 10.1016/j.conbuildmat.2018.03.123
Google Scholar

Brown P., Bothe J., Jr.: The system CaO-Al2O3-CaCl2-H2O at 23±2 °C and the mechanisms of chloride binding in concrete. Cement and Concrete Research, 34, 9, 2004, 1549-1553, DOI: 10.1016/j.cemconres.2004.03.011
Google Scholar

Jóźwiak-Niedźwiedzka D., Antolik A., Dziedzic K., Glinicki M.A., Gibas K.: Resistance of selected aggregates from igneous rocks to alkali-silica reaction: verification. Roads and Bridges - Drogi i Mosty, 18, 1, 2019, 67-83, DOI: 10.7409/rabdim.019.005
Google Scholar

Rajabipour F., Giannini E., Dunant C., Ideker J.H., Thomas M.D.D.: Alkali-silica reaction: Current understanding of the reaction mechanisms and the knowledge gaps. Cement and Concrete Research, 76, 2015, 130-146, DOI: 10.1016/j.cemconres.2015.05.024
Google Scholar

Csizmadia J., Balázs G., Tamás F.D.: Chloride ion binding capacity of aluminoferrites. Cement and Concrete Research, 31, 4, 2001, 577-588, DOI: 10.1016/S0008-8846(01)00458-6
Google Scholar

Qiao C., Suraneni P., Weiss J.: Flexural strength reduction of cement pastes exposed to CaCl2 solutions, Cement and Concrete Composites, 86, 2018, 297-305, DOI: 10.1016/j.cemconcomp.2017.11.021
Google Scholar

Valenza J.J., Vitousek S., Scherer G.W.: Expansion of hardened cement paste in saline solutions, creep, shrinkage and durability mechanics of concrete and other quasi-brittle materials, London, 2005, 207-212.
Google Scholar

Dąbrowska M., Giegiczny Z.: Chemical resistance of mortars made of cements with calcerous fly ash. Roads and Bridges - Drogi i Mosty, 12, 2, 2013, 131-146, DOI: 10.7409/rabdim.013.010
Google Scholar

Suryavanshi A.K., Narayan Swamy R.: Stability of Friedel’s salt in carbonated concrete structural elements. Cement and Concrete Research, 26, 5, 1996, 729-741, DOI: 10.1016/S0008-8846(96)85010-1
Google Scholar

Sutter L., Peterson K., Touton S., Van Dam T., Johnston D.: Petrographic evidence of calcium oxychloride formation in mortars exposed to magnesium chloride solution. Cement and Concrete Research, 36, 8, 2006, 1533-1541, DOI: 10.1016/j.cemconres.2006.05.022
Google Scholar

Peterson K., Julio-Betancourt G., Sutter L., Hooton R.D., Johnston D.: Observations of chloride ingress and calcium oxychloride formation in laboratory concrete and mortar at 5°C. Cement and Concrete Research, 45, 2013, 79-90, DOI: 10.1016/j.cemconres.2013.01.001
Google Scholar

Santagata M.C., Collepardi M.: The effect of CMA deicers on concrete properties. Cement and Concrete Research, 30, 9, 2000, 1389-1394, DOI: 10.1016/S0008-8846(00)00334-3
Google Scholar

Bassuoni M.T., Rahman M.M.: Response of concrete to accelerated physical salt attack exposure. Cement and Concrete Research, 79, 2016, 395-408, DOI: 10.1016/j.cemconres.2015.02.006
Google Scholar

Balonis M.: Thermodynamic modelling of temperature effects on the mineralogy of Portland cement systems containing chloride. Cement and Concrete Research, 120, 2019, 66-76, DOI: 10.1016/j.cemconres.2019.03.011
Google Scholar

EN 206: Concrete, performance, production and conformity, The Czech Republic (2018)
Google Scholar

CSN 731326: Resistance of cement concrete surface to water and defrosting chemicals, The Czech Republic (1984)
Google Scholar

CSN EN 12390-3: Testing hardened concrete - Part 3: Compressive strength of test specimens, The Czech Republic (2009)
Google Scholar

CSN EN 12390-6: Testing hardened concrete - Part 6: Tensile splitting strength of test specimens, The Czech Republic (2009)
Google Scholar

Liu J., Miao C., Chen C., Liu J., Cui G.: Effect and mechanism of controlled permeable formwork on concrete water adsorption. Construction and Building Materials, 39, 2013, 129-133, DOI; 10.1016/j.conbuildmat.2012.05.005
Google Scholar

Chan S.Y., Ji X.: Comparative study of the initial surface absorption and chloride diffusion of high performance zeolite, silica fume and PFA concretes. Cement and Concrete Composites, 21, 4, 1999, 293-300, DOI: 10.1016/s0958-9465(99)00010-4
Google Scholar

Claisse P.A.: Surface tests to determine transport properties of concrete - I: the tests, in: Transport Properties of Concrete, Elsevier, 2014, 26-42, DOI: 10.1533/9781782423195.26
Google Scholar

Ghazy A., Bassuoni M.T.: Resistance of concrete to different exposures with chloride-based salts. Cement and Concrete Research, 101, 2017, 144-158, DOI: 10.1016/j.cemconres.2017.09.001
Google Scholar

Bernal J., Fenaux M., Moragues A., Reyes E., Gálvez J.C.: Study of chloride penetration in concretes exposed to high-mountain weather conditions with presence of deicing salts. Construction and Building Materials, 127, 2016, 971-983, DOI: 10.1016/j.conbuildmat.2016.09.148
Google Scholar

Suraneni P., Monical J., Unal E., Farnam Y., Weiss J.: Calcium Oxychloride Formation Potential in Cementitious Pastes Exposed to Blends of Deicing Salt. ACI Materials Journal, 114, 4, 2017, DOI: 10.14359/51689607
Google Scholar

Otieno M., Beushausen H., Alexander M.: Chloride-induced corrosion of steel in cracked concrete - Part I: Experimental studies under accelerated and natural marine environments. Cement and Concrete Research, 79, 2016, 373-385, DOI: 10.1016/j.cemconres.2015.08.009
Google Scholar

Hájková K., Šmilauer V., Jendele L., Červenka J.: Prediction of reinforcement corrosion due to chloride ingress and its effects on serviceability. Engineering Structures, 174, 2018, 768-777, DOI: 10.1016/j.engstruct.2018.08.006
Google Scholar

Gao Y., Zhang J., Zhang S., Zhang Y.: Probability distribution of convection zone depth of chloride in concrete in a marine tidal environment. Construction and Building Materials, 140, 2017, 485-495, DOI: 10.1016/j.conbuildmat.2017.02.134
Google Scholar

Kwon S.J., Na U.J., Park S.S., Jung S.H.: Service life prediction of concrete wharves with early-aged crack: Probabilistic approach for chloride diffusion. Structural Safety, 31, 1, 2009, 75-83, DOI: 10.1016/j.strusafe.2008.03.004
Google Scholar

Shi J., Ming J., Sun W., Zhang Y.: Corrosion performance of reinforcing steel in concrete under simultaneous flexural load and chlorides attack. Construction and Building Materials, 149, 2017, 315-326, DOI: 10.1016/j.conbuildmat.2017.05.092
Google Scholar

Reiterman P.: Influence of metakaolin additive and nanoparticle surface treatment on the durability of white cement based concrete. European Journal of Environmental and Civil Engineering, 2018, DOI: 10.1080/19648189.2018.1504235
Google Scholar

Kurda R., de Brito J., Silvestre J.D.: Influence of recycled aggregates and high contents of fly ash on concrete fresh properties. Cement and Concrete Composites, 84, 2017, 198-213, DOI: 10.1016/j.cemconcomp.2017.09.009
Google Scholar

Shon C.S., Abdigaliyev A., Bagitova S., Chung C.W., Kim D.: Determination of air-void system and modified frost resistance number for freeze-thaw resistance evaluation of ternary blended concrete made of ordinary Portland cement/silica fume/class F fly ash. Cold Regions Science and Technology, 155, 2018, 127-136, DOI: 10.1016/j.coldregions.2018.08.003
Google Scholar

Glinicki M.A., Jaskulski R., Dąbrowski M.: Design principles and testing of internal frost resistance of concrete for road structures. Roads and Bridges - Drogi i Mosty, 15, 1, 2016, 21-43, DOI: 10.7409/rabdim.016.002
Google Scholar

Reiterman P., Holčapek O., Zobal O., Keppert M.: Freeze-thaw resistance of cement screed with various supplementary cementitious materials. Reviews on advanced materials science, 58, 1, 2019, 66-74, DOI: 10.1515/rams-2019-0006
Google Scholar

Bilek V., Mec P., Zidek L., Moravec T.: Concretes with ternary binders - thinking about frost resistance. Cement, Wapno, Beton, 20, 2015, 72-78
Google Scholar

Ye H., Jin X., Fu C., Jin N., Xu Y., Huang T.: Chloride penetration in concrete exposed to cyclic drying-wetting and carbonation. Construction and Building Materials, 112, 2016, 457-463, DOI: 10.1016/j.conbuildmat.2016.02.194
Google Scholar

Farnam Y., Villani C., Washington T., Spence M., Jain J., Weiss J.W.: Performance of carbonated calcium silicate based cement pastes and mortars exposed to NaCl and MgCl2 de-icing salt. Construction and Building Materials, 111, 2016, 63-71, DOI: 10.1016/j.conbuildmat.2016.02.098
Google Scholar

Pavel Reiterman

pavel.reiterman@fsv.cvut.cz

Affiliation:

Czech Technical University in Prague, Faculty of Civil Engineering, Thakurova 7, 166 29, Prague, Czech Republic

Martin Keppert

Affiliation:

Czech Technical University in Prague, Faculty of Civil Engineering, Thakurova 7, 166 29, Prague, Czech Republic

Effect of various de-icers containing chloride ions on scaling resistance and chloride penetration depth of highway concrete

Abstract

Keywords:

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Martin Keppert